Clean-up of a pesticide-lanolin mixture by gel permeation chromatography.

نویسندگان

  • M López-Mesas
  • M Crespi
  • J Brach
  • J P Mullender
چکیده

In this study, the efficiency of a clean-up method by gel permeation chromatography (GPC) for the separation of pesticides from lanolin is analyzed. The pesticides analyzed belong to two different families, organophosphorous and synthetic pyrethroids. Lanolin, a standard mixture of the pesticides, and a lanolin-pesticides mixture are injected in a GPC column. The recoveries and elution times from the GPC column of lanolin (by a gravimetric method) and pesticides (by gas chromatography-electron capture detector) are determined. From this column, a good separation of the lanolin-pesticides mixture is observed.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Recent Developments in Clean up Techniques of Pesticide Residue Analysis for Toxicology Study: A Critical Review

Clean up is one of the most important steps to remove co-extractives and undesired interfering substances from the sample before analysis in pesticide residue analysis. Some advanced, sophisticated and efficient methods of clean up have emerged out which is able to save time as well as amount of solvents. These are Solid Phase Extraction (SPE), Gel Permeation Chromatography (GPC) and Supercriti...

متن کامل

Analysis of pesticides in lanolin by gel permeation chromatography and gas chromatography

In this paper the efficiency of a method for the separation and identification of pesticides in lanolin is presented. Theses pesticides belong to the organophosphorous and synthetic pyrethroids families. After the gel permeation chromatography, pesticides are separated from lanolin into two fractions corresponding to the two families, which simplify subsequent analysis by gas chromatography.

متن کامل

Determination of Organophosphorus Pesticide Residues in the Liver by Gas Chromatography with Flame Photometric Detection

A method for simultaneous determination of residues of six organophosphorus pesticides in animal liver samples has been developed and validated. The method is based on the extraction of organophosphorus pesticides with a mixture of acetone-petroleum ether, clean up on a gel permeation chromatography, further clean up on a small silica gel column, and finally determination by gas chromatography ...

متن کامل

Pesticide residue analyses in plant material by chromatographic methods: clean-up procedures and selective detectors.

This paper deals with the analysis of pesticide residues by chromatographic methods in samples of plant origin. Emphasis is put on the isolation and clean-up steps of the sample preparation for GC or LC determination. The problems of the extraction solvent selection and clean-up procedures using different types of adsorption column chromatography or gel permeation chromatography are discussed. ...

متن کامل

Gel Permeation Chromatography Purification and Gas Chromatography-Mass Spectrometry Detection of Multi-Pesticide Residues in Traditional Chinese Medicine

The measurement of 23 organochlorine, organophosphorus, and pyrethroid pesticides in typical traditional Chinese medicine (TCM), flos lonicerae, was made using gel permeation chromatography (GPC) purification and gas chromatography-mass spectrometry (GC-MS) detection. The pesticides were extracted with ultrasonic device and 5.0 mL mixture of ethyl acetate and cyclohexane (1:1, v/v). Coextractan...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Journal of chromatographic science

دوره 38 12  شماره 

صفحات  -

تاریخ انتشار 2000